Water + Salt + Energy = Clean! 374
codesmith.ca writes "CTV News is reporting about a device built at the Russian Institute for Medical Engineering that can convert standard water and salt into an antimicrobial solution. Apparently it's works on almost anything (virii, bacteria, cysts...) and it's safe for human consumption to boot. I can't find a site for the institute, but there are articles around. This one is fairly detailed, but hard to reach. Here's the Google cache. Here's one about a paper shows it's not exactly super-new technology." Any chemist care to comment on what sounds to be too good to be true?
i think we know where this is going (Score:2)
cool (Score:2, Funny)
does this mean that windows machines will be virus free from now on??
Re:cool (Score:4, Funny)
does this mean that windows machines will be virus free from now on??
I guarentee you that if you pour the solution into your computer, it will be free of viruses from now on. Should work on any operating system
OK Disclaimer-- don't try this at home, or if you do, don't complain to me
Correction... (Score:2, Funny)
ALL links in Slashdot are hard to reach. This one is just soon to be impossible to reach.
Am I the only one... (Score:2)
1. Claim to have invented salt water
Re:Am I the only one... (Score:2)
Me too! (Score:5, Funny)
Re:Me too! (Score:5, Funny)
If this is so good for you (Score:2)
Just a Swimming-Pool Chlorine Generator? (Score:4, Informative)
no electricity needed. (Score:2)
Re:no electricity needed. (Score:2)
Ooh, that smarts (Score:2)
Re:Just a Swimming-Pool Chlorine Generator? (Score:3, Informative)
http://www.watermaid.com.au
for one. There are quite a few others, too. Just throw "salt water chlorination" into google.
Re:Just a Swimming-Pool Chlorine Generator? (Score:5, Interesting)
The Cl- ions form chlorine gas> If you can keep it involved in the water, the whole thing works. It does, however, produce lots of NAOH, which is not a nice thing to have around either!
Oh, and the design I used (I found it somewhere around town) used asbestos to separate the positive and negative regions.
In general, it was your all around chemical warfare and carcinogenic dream!
Re:Just a Swimming-Pool Chlorine Generator? (Score:3, Funny)
Of course it leaked chlorine gas, you forgot to stabilize the reaction with dioxin. You also need to use lead pipes.
-
Re:Just a Swimming-Pool Chlorine Generator? (Score:2, Informative)
That scares the hell out of me (Score:4, Interesting)
A while ago I read Neal Stephenson's Zodiac, which mentions chlorene. This post rang a bell, so I dug it up and pawed through it to find what it had to say. The book only tells you about the situation in bits and pieces, so this really took some searching:
Ionic chlorene's easy to get. It's in seawater. If you want to manufacture a whole catalog of industrial chemicals, you have to convert ionic chlorine into the covalent variety. You do that by subtracting an electron.
And it's just about that simple. You take a tank of seawater and you put a couple of bare wires into it. You hook up a source of electrical power up between the wires, and current - a stream of electrons - flows through the water. The molecules get rearranged. The ionic chlorine turns into the covalent kind, which is what you want. The sodium joins up with fractured water molecules to form sodium hydroxide. Or lye and alkali, depending on how educated you are.
If you're an engineer, and you're not very bright, it's easy to love polychlorinated biphenyls. They are cheap, stable, and easy to make and they take heat very well. That's why they end up in heat exchangers and electrical transformers. It's how they got into that machine in Japan and, when the pipes started to leak, it's how they got into a lot of rice oil.
Unfortunately, rice oil is for human consumption, and as soon as humans enter the equation, PCBs no longer look very good. The problem with humans is that they have a lot of fat in their bodies, and PCBs have this vicious affinity for fat. They dissolve themselves in human fat cells and they never leave. They are studded with loose chlorine atoms that know how to break up chromosomes. So when that heat exchanger started leaking, the city of Kusho, Japan started to look like the site of a Biblical plague. Newborn babies came out undersized and dark brown. People started to waste away. They developed a fairly disgusting skin rash called chloracne and felt very sick.
A benzene ring is a six-pack of carbon atoms. The six-pack is held together. It's stable. It's strong. It takes some effort to pull one of the atoms off. There are a couple different kinds. If you put two six-packs together, you have a twelve-pack. THe six-packs are phenyls, a twelve-pack is a biphenyl. If the six-packs are benzenes, it's a dibenzodioxin, because the connection between the six-packs is made by using a couple of oxygen atoms. But the toxic part of polychlorinated dibenzodioxin (PCDDs) and polychlorinated biphenyls (PCBs) is the chlorine.
The biphenyl or dibenzodioxin structure dissolves easily in fat. Once it gets into your body fat, it never leaves.
The second bad thing is, the chlorine there is in covalent form; it's got the normal number of electrons, whereas the chlorine in (safe) table salt is in ionic form. It's got an extra electron. The difference is that covalent chlorine is more reactive; it has these big electron clouds that can f*** up your chromosomes. And it slips right through your cell membranes. Ionic chlorine ddoesn't - the cell membranes are made to stop it.
In Stephenson's book, this guy Sangamon Taylor runs around trying to take down corporations that electrocute seawater to create PCBs, use the PCBs as coolant, then dump them into Boston harbor. Stephenson makes it seem like the root of all evil is zapping salt water, because it produces organic chlorine. So I would be very, very careful about intentionally electrocuting salt water and then swimming in it.
It seems like there must be something more to this if, as you said, "This Old House" recommended the process. Maybe it works differently with plain salt water as opposed to sea water. Or something. Scares the crap out of me, though. Maybe someone smarter can tell me what I'm talking about?
This thing makes no sense (Score:2)
Has anyone seen a more detailed description of how this thing actually works? It can't be as simple as the article describes, solutions just don't work that way.
You are forgetting the sodium (Score:2)
I don't see how it would be safe for humans, but whatever.
Re:that would be (Score:2)
I don't think the concentration is likely to get to that range by decomposing salt water.
Re:It makes some sense... (Score:2, Insightful)
Look, unless you believe in alchemy and slow retort cooking under the full moon, the only thing you're going to get from this contraption is Hydrochloric Acid and Sodium Hydroxide, a strong acid and a strong base (alkali), both of which have antibacterial properties. From the technical description of the actual device, it looks like they're using some kind of ceramic membrane to prevent the positive hydrogen ions and the negative hydroxyl radicals from actually recombining with the Sodium Chloride to form the respective acid and base, so what you end up with are free hydrogen radicals (basically just free protons) and free hydroxyl radicals (basically water that's missing a proton). Neither of these is safe in any sense I can imagine. I certainly wouldn't want to be around if the two products came into contact with NaCl by accident. Heat, Light, Boom, Burn! Or maybe just a slow dermal sizzle.
There's a real pastiche of data here. Variations on a theme mixed together in a haphazard way. None of which adds up to what the CTV article suggests. What you get when you send a reporter to cover a technical story.
Useful technology no doubt, but nothing you'd want to drink.
Re:It makes some sense...(part deux) (Score:2)
Will Cl- ions react with a microscopic organism? I mean, Cl- ions are already present in sea water (albeit not in as high concentrations) and there are plenty of microbes in the sea....same deal with sodium ions.
Re:It makes some sense...(part deux) (Score:2)
Really? (Score:2)
It may also interest you to know that even oxygen can be poisonous [howstuffworks.com]. (-:
Perhaps you should have qualified yourself with `large concentrations of chlorine...' - even if only to reduce `period pain'.
Re:It makes some sense...(part deux) (Score:2)
Gastric juices are, for the most part, 1M HCl...so every liter of stomach acid your body produces requires about 35.5 grams of chloride ion, (about 58 g of table salt)
There's even an FDA recommended daily allowance of sodium chloride that correlates to that. (they know how long it takes your body to make 1 liter of stomach acid...I don't)
Re:It makes some sense...(part deux) (Score:2)
Meaux (Score:2)
Re:Meaux (Score:2, Funny)
Hmm... I'm sceptical. (Score:3, Insightful)
Let's have a look at that CTV report:
The resulting solution is so energy rich, it dissolves all microbes it comes in contact with, in water, on objects and on human skin. It also happens to be odorless, colorless, and completely safe for human consumption.
It dissolves microbes, but is safe for human consumption? Is anyone else not convinced?
Researchers said the technique used to control bacteria, viruses, cysts and germs is 200 to 300 times more efficient than any other purification alternative.
200 to 300 times more efficient, how, exactly? And what does it do to help cysts?
(and, er, what's the difference between a virus and a germ?)
The process is cheap. It costs just fractions of a penny to purify a litre of water. Researchers have even been able to take spoiled milk and, by passing it through the Emerald, make it fresh once again. Sounds like science fiction, doesn't it?
Yep... it does. Sorry.
Re:Hmm... I'm sceptical. (Score:2)
Difference between a virus and a germ (Score:3, Insightful)
A virus is basically a self replicating (with a hosts help) package of RNA.
A germ (or bacteria) is a single celled organism.
Here's the problem as I see it. "spoiled" milk is not JUST caused by bacterial action. It's also a chemical conversion of lactose and lipids. Unless this stuff is some Uber-Converter that can reverse time, this story is full of crap. Now, it COULD have enough energy to 'dissolve' the biological matter present in it. Hell, if I put a huge current though an ionic solution, I can almost guarantee everything in it is going to be toast too.
That's not remarkable, that's bad swimming pool pump maintenace.
Re:Hmm... I'm sceptical. (Score:2)
Iocaine powder!
Oops...never mind.
A more balanced description (Score:5, Informative)
http://www.fwr.org/wrcsa/832100.htm
It's plain simple ... (Score:5, Informative)
Freshman chemistry tells you:
NaCl -> Na+ + Cl-
H2O -> H+ + HO- (actually H3O+ instead of H+ but that's details)
Then, you add some electricity and you get:
At cathode (- electrode), H+ -> H2 (bubbles out) which means a lot of Na+ and HO- are left floating around - thus, per Google cached article in the original post: "The catholyte is a powerful alkaline solution used for [...]" -- not surprising at all, as you can see
Then, at anode (+ electrode) you've got HO- and Cl-
Cl2 + NaOH -> NaCl + NaClO
Now what does the article say?
Damn that highschool chem
END-OF-CHEM-LESSON
I've seen something simliar. (Score:2)
No one could believe it worked. All they did was add salt to water and run a charge through it. All it made was salty water. Despite the manufacturers claim of disinfection, they couldn't verify it.
I'm not a chemist by any means, but the only thing we could think of was that it created Na+ and Cl- ions, causing some sort of disinfection on contact. Which is believeable, because that's how your home pool works. Interesting....
This is SO snake-oil (Score:5, Interesting)
This is an experiment I did in elementary school.
It's called electrolysis. You separate salt water into
Use enough voltage, and maybe you bump oxygen to ozone, a superoxidizer (see above).
None of this takes any kind of chemist to see.
Note also that these chemicals are extremely hazardous in their uncombined forms. Remember Apollo 1 and its pure oxygen atmosphere at full sea-level pressure? Skin catches fire almost explosively in that sort of atmosphere - it's truly horrible what pure oxygen can do. Combine hydrogen and oxygen in the right proportions and they will explode. Sodium is poison and explosive when combined with water. Chlorine is poision.
Some of the more recent explorations into silver as a disinfectant with good tolerance in the body might be more profitable to follow, but also have snake-oil potential because too few people recognize that as another century-old technology that has a mass-market application in swimming pools today.
Were I you guys, I'd kill the story.
Bruce
Re:This is SO snake-oil (Score:2)
Those right proportions are 2 hydrogens for every oxygen. The explosion is from the energy being released. Which is almost as much energy as it took to crack the hydrogen from the oxygen in the first place.
Oh yeah, when the energy is released you have water again, I hope there is some sodium around at that time.
Well... (Score:2)
Re:This is SO snake-oil (Score:2, Informative)
Dammit.
Sodium (Na) and the sodium ion (Na+) are not the same thing. Salt is an ionic compound; when I dissolve it in water, I get water and a whole bunch of dissolved Na+ and Cl-. They're ions, which behave chemically in a fashion distinct from the full atom, which is why the glass of salt water doesn't explode and why I don't oxidize my esophagus if I drink it.
Re:This is SO snake-oil (Score:2)
Bruce
Re:This is SO snake-oil (Score:4, Informative)
Hydrogen a highly-reactive gas, thus antibiotic.
Oxygen, an oxidizer (duh), oxidation is about the most commonly used method of disinfection.
Sodium, a highly reactive chemical and thus disinfectant.
Chlorine, a superoxidizer (see above).
Actually, you just get the most easily reduced/oxidized species coming out. This means chlorine and hydrogen. The water stays water, and the sodium displaces the removed hydrogen to form sodium hydroxide. So, your saltwater turns into oven cleaner, which is not safe to drink, and you get chlorine gas bubbling off, which works quite well as a disinfectant (and is already used).
I wouldn't worry about the hydrogen. It's not terribly reactive, contrary to what you appear to have heard. It does burn, but you won't have enough present to worry about.
If they're using this for disinfecting, what's probably happening is that they're producing sodium chlorate. This can be formed instead of chlorine gas if your electrodes are close enough together that the ion species can mix. Sodium chlorate is a strong oxidizing agent; in weak solutions, it should be a decent disinfectant. I *really* wouldn't drink it, though (it's poisonous in significant amounts).
Contrary to what the article says, I seriously doubt you could mist a letter with chlorate-rich water and have it stay dry while being disinfected. You'd also have the nasty side effect of the letter becoming quite flammable when the mist dried, if you sprayed any substantial amount of solution on it (powerful oxidizer, remember; unstable enough that it can even explode on its own if provoked enough).
Alternatively, they could just be doing standard electrolysis and burning the hydrogen and chlorine together to get hydrogen chloride. On contact with water (or bacteria) it'll turn into hydrochloric acid, and so would be quite poisonous.
Or they could be arcing through the air using the water as an electrode, to produce ozone or nitric acid vapour. The salt wouldn't be doing much in this scenario (except making the water conduct).
In summary, the possible reaction paths are a bit more complicated than you're painting, though I agree that the article's claims are at the very least exaggerated.
Re:This is SO snake-oil (Score:2)
To take this past the point of absurdity, you would eventually run out of the easily reduced substances :-) . And yes, it's silly to expect all of those ingredients to stay elemental.
Thanks
Bruce
Re:This is SO snake-oil (Score:2)
> You'd also have the nasty side effect of the letter becoming quite flammable when the mist dried, if you sprayed any substantial amount of solution on it (powerful oxidizer, remember
Used to be widely sold in the UK as a weedkiller and occasionally used by schoolchildren to make explosives. Now only sold with added fire retardant because of the IRA.
Trivial details... (Score:5, Informative)
Unfortunately, some of the things Bruce has stated are not entirely accurate. The general facts are correct. but some bits need modification.
Hydrogen is reactive. It's only 'highly' reactive if you haven't played with really reactive stuff, like fluorine, chlorine and, er, oxygen. Potasium is fun too.. (I have only seen Cesium once. That's quite enough).
Skin only catches fire if you get it very hot. An uncontrolled fire in a pure oxygen atmosphere is more likely to vaporize the skin; then the fat underneath will start to burn. Pure oxygen at reasonable (3atm) pressure will not cause spontaneous combustion of people. But if a fire starts in that environment, then you won't be able to put it out. The fire in Apollo 1 was not spontaneous. It was started by an electrical fault. The three astronauts suffocated in flame. Not nice.
You can happily mix hydrogen and oxygen in a 2:1 ratio. You can pressurize the mixture to astonishing levels. If there's a lot less oxygen, you can breathe the mixture for days at a time (google for "deep hydrogen diving"). If you make a spark, then you'll understand just how reactive oxygen is. The lesson learnt will be very short, and terminally instructive.
But hydrogen and oxygen are not hypergolic. Ask a rocket scientist. Even the Space Shuttle needs a match to get it going.
Sodium is a disinfectant. In the same way that a raging forest fire is disinfectant. Kids! treating your grazed knees with sodium metal may sting! Also, your parent's lawyers will have to contend with a stupidity counter-claim.
Oxidizing agents and reducing agents are defined by their ability to grab or release electrons.
If you want to understand this stuff, find somebody who knows what "Gibb's free energy" is about. Then, get them to explain it to me...
Re:Trivial details... (Rockets!) (Score:2)
Of course.. and everyone knows that an annoying NASA robot can start just one to force a launch. [imdb.com]
Re:This is SO snake-oil (Score:2)
The sodium will combine with the water to produce lye.
The hydrogen will go away.
The chlorine will go away, but more slowly. Some of it will combine with the water to product HCl. This will combine with the lye to give salt water.
It might well be a decent disinfectant, at the right voltage. And if it's weak enough, I suppose it would be approximately harmless. Disinfectants don't need to be particularly strong solutions... but I would tend to avoid using lye.
Re:This is SO snake-oil (Score:2)
Bruce
Re:This is SO snake-oil (Score:2)
588 units, 44 prefixes
You have: 1 mole
You want:
* 6.0221367e+23
Re:This is SO snake-oil (Score:2)
Re:This is SO snake-oil (Score:3, Informative)
OIL RIG
Oxidation is Loss (of electron) Reduction Is Gain (of electron)
Anything atom or molecule that gives up an electron in a reaction is an oxidizer. Anything that gains or takes an electron is a reducer/reducing agent. They're paired reactions.
Oxygen can be either a reducer or an oxidizer, depending on the reaction and its starting oxidation state.
Thank goodness for B. Perens and the post right above his debunking this 'breakthrough' chemistry as high school chemistry lab exercises.
I was beginning to worry that I would have to do it myself, and they did it much better.
Marcus
Re:This is SO snake-oil (Score:3, Informative)
Oxidation is an increase in oxidation number. If a species increases in oxidation number, it has oxidized, regardless of whether or not oxygen was involved.
Take a portion of finely divided sodium metal. Spray some hot chlorine gas over it. You'll get an oxidation-reduction reaction. Like this:
2Na + Cl2 --> 2NaCl
Na's oxidation number goes from 0 to +1, so it's been oxidized. What did the oxidation? Well, there's no oxygen, so it must have been the chlorine. Chlorine therefore was an oxidizer in this reaction. The Cl went from 0 to -1, so it was reduced. This was a redox reaction.
It involved no oxygen. Sheesh.
Re:This is SO snake-oil (Score:2)
And, obviously, because you said that, you are not a fool. That's nice.
Obviously, you're too busy to post a response to this, since you're the only non-fool on the planet.
As such, your income from your inventions must be measured in billions a year.
Merely juggling the millions around must take hours every week.
Inventing new things must take up the rest of your time. However, if you can spare a moment, could you tell me how to stop posting asinine and insulting comments on Slashdot?
It is my dream that you will find time to read this comment. If you do, I shall know that I have communicated with a truly superior person.
Foolishly yours,
ChazR
Re:This is SO snake-oil (Score:2)
I take it you know diving the way that Bruce knows chemistry? If you are certified, but don't know your partial pressures, I hope I never have you as a dive buddy.
Oxygen is toxic to humans at a partial pressure of 2.0, which is why divers shoot for a partial pressure of 1.2 to 1.4 at max depth when diving on a Nitrox mix.
100% pure oxygen at 2atm is a partial pressure of 2.0, so the diver you stuffed in the hyperbaric chamber would be dead by the time you got them to 3atm.
-Chris
Re:This is SO snake-oil (Score:2)
It IS toxic, though, and bad things can happen if this is kept up too long.
Re:This is SO snake-oil (Score:2)
Anti-anthrax (Score:2)
Chemistry lesson time (Score:2)
What makes me suspicious of the Emerald device is the following line:
"The catholyte is a powerful alkaline solution used for treating industrial effluent like the ones from Electro-plating, photographic, and/or textile plants. Catholyte has powerful properties for flocculation, coagulation, bionutrient transfer, cleaning purposes, and neutralizing the toxicity of heavy metals."
Ok, if the catholyte is a powerful alkaline solution, it then follows that the anolyte is a powerful acid solution. Can't make one without the other. And powerful acid solutions aren't exactly benign.
Science News had an article on this... (Score:5, Informative)
NaCl + 2H20 + electricity -> Na + Cl + 2H2 + O2
Rather, you get a hypochlorous acid ion, an a sodium hydroxide ion. In effect, the reverse of mixing hypochlorous acid and lye.
However, you get it in VERY dilute quantities, nowhere near what you'd need to damage human skin. But if you are an itty bitty microbe, the oxidizing effect is deadly.
Really, this is just a "bleach on demand" sort of thing.
Re:Science News had an article on this... (Score:2)
However, many posters assert that you will get metallic sodium and pure chlorine in the mix, and that is wrong.
As any chemist will tell you, when you mix NaCl into H20, you will have Na+ and Cl- ions in the water - no electricity needed. However, remove the water and the NaCl will reform.
What the electrolysis reaction does is break the H2O into H+ and OH- ions. Some of the H+ ions will combine into H2 at at the negative electrode, and some of tho OH- ions will combine into O2 and H2O at the plus electrode, releasing the commonly observed gases.
However, some of the H+ ions will also combine with the CL- ions to yeild HCL, which will furthur react to produce hypochlorus acid (which, if you had studied anything more than basic chemistry, you would recognise as bleach).
Additionally, some of the OH- ions will react with the Na+ ions to form NaOH.
Now, this is NOT an equilibrium state - in the absense of the electric current the hypochlorous acid will recombine with the sodium hydroxide to reform water and salt. Hence why you have to seperate the solutions at the electrodes - yeilding a mild bleach solution and a mild lye solution.
Y
A clear and concise explanation... (Score:3, Interesting)
No doubt the electric field applied causes small bubbles to form within the solution, and then rapidly collapse. This collapse leads to extroardinarily high temperatures and pressures, which in turn cause nuclear fusion to take place. Stray gammas generated by this fusion result in the destruction of nearby pathogens.
Seriously, this technique sounds like a load of crap, for the most part. I can buy the electrochemical action bit, sort of. Pure molten NaCl (salt, hereafter) will electrolyze to form sodium and chlorine gas, sure enough. With a little creative engineering, it is possible to separate these to products and collect them for later use. Indeed, this is exactly what is done for commercial production of these two elements.
On contact with water, pure Na will form a solution of (aggressively basic) sodium hydroxide plus some hydrogen gas. (This, I assume, is the catholyte we hear about.) Chlorine in water forms an acidic solution which is, to be fair, definitely germicidal.
I see two problems. The first is technical. In a water solution, the electrolytic yields of sodium and chlorine are typically both very low, because oxygen and hydrogen gas are preferentially formed first. (There are sound thermodynamic reasons for this.) Maybe these experimenters have gotten around this somehow, perhaps using exotic catalysts or something.
The second problem is a bit more difficult. If the two component solutions (sodium + water and chlorine + water) are kept separate, individually they would be quite toxic. Brought together, there is a very quick reaction that brings us right back to salt and water--not a particularly powerful disinfectant, and what we started with before we had a mystical black box.
I can think of some other more creative possibilities, as well. Perhaps they're talking about generating some sort of activated state oxygen to do the dirty work (the salt just makes the water conductive)--in which case, they're definitely frauds. There just aren't any activated oxygen states that are stable long enough (in water) to get to the surface to be disinfected. Atomic oxygen might do it, but that's already been invented--and I'm pretty sure it won't last very long in solution either.
Finally, from the article, we have the quote:
f a letter is suspected of containing anthrax spores, it could be passed through a dry mist made from the Emerald solution and the letter would be sterilized.
The letter wouldn't even get wet. Anyone exposed to the spores could bathe in the solution and be germ free.
Erm. Dry mist. Sure. What's in this dry mist, exactly? Chlorine? Nope--it's way toxic. Sodium? Nope--it's a metal. Hydrogen? Um. Yeah. Oxygen--maybe, but atomic oxygen generators already exist (they're used for restoring artwork and whitening teeth). Singlet oxygen will kill things, but it only lasts a few nanoseconds in water.
So, to conclude this lengthy post--I call bullshit!
Re:A clear and concise explanation... (Score:2)
This device, through the small quantities of chlorine plus nasty (biochemically speaking) radicals generated through normal water electrolysis will probably very easily kill nearly anything that's actually in the water that passes through the device. I stand by my assertion that there is little or no residual purifying ability to the liquid that comes out, and the notion that a "dry mist" (whatever that is) from it will kill anthrax sounds like nonsense.
High School Chemistry (Score:4, Informative)
Oh the pain! The people complaining about the state of science education in the US are RIGHT!!
Electrolysis of salt solution produces a solution of sodium hypochlorite, similar to Clorox bleach. Nothing wrong with that, this is a GREAT disinfectant. But new technology? I DON'T THINK SO. We have been chlorinating water supplies since 1908 or so.
Some technological historians believe that the addition of chlorine to drinking water is the primary reason for increased life expectancies in the 20th century, and claim that this one innovation has done more to prevent disease than the rest of modern medicine combined.
Here are the reactions:
anode: 2Cl- = Cl2(aq) + 2e-
cathode: 2e- + 2Na+ + 2H20 = H2(g) + 2NaOH
2NaOH + Cl2 = 2NaOCl + 2H+
To stabilize the NaOCl it is best to add a bit extra NaOH. (See LeChatlier).
You can use the H2 to power your laptop. (See fuel cells.)
Re:High School Chemistry (Score:2, Interesting)
While your chemistry is correct, this is not the reaction they are talking about. The production of sodium hypochlorite is not an electrochemical process. It takes place without the aid of an electrical current. This is why NaOH is commonly used as a scrubbing fluid to remove Cl2 from a gas stream.
The reaction we are talking about is the electrolysis of salt water:
H20 + NaCl + electricity -> NaOH + Cl2 + H2
A mixture of chlorine gas and weak brine called the anolyte leaves the cell on one side, and the caustic soda (NaOH) and hydrogen gas mixture called the catholyte leaves on the other.
errr Publik edumacation not what it used to be (Score:2)
How this works (Score:2)
If you electrify the salt water, they separate. If you turn off the power, they recombine. Anything that was near one side or the other will be pretty effectively fried. Of course, you're not going to entirely separate them, so there's a middle section where it's still just salt water. This device does some fluid mechanics and such to pass anything that is in the incoming water through both regions before the water (now recombined) comes out of the device. It's actually a bit of tricky engineering to make sure that absolutely nothing can get through without going through both regions, which is what this is all about.
The electrolysis experiment is trivial. The trick is being thorough when you've got water flowing through.
Making milk fresh again? (Score:2)
I use this in my backyard (Score:3, Informative)
The water in the pool is kept slightly salty. The pump/filter system then add electricity to the water in a controlled manner that causes the salt and water to "decompose" in to the constituent molecules that are deadly to bacteria (mainly chlorine and sodium). As the water leaves the control area the molecules recombine (mostly) to form salt water again. Some chlorine remains free and circulates in the pool.
the only thing different about the Russian system seems to be they may use more power as the story claims the device "dissolves"microbes. Then again chlorine "dissolves" microbes through oxidation.
folks, look up the plural of "virus" (Score:2)
"Virii" isn't not a Latin plural of any known word. The most plausible latin nominative plural would be "viri" [nd.edu], but some people don't buy that [perl.com].
Re:folks, look up the plural of "virus" (Score:2)
Never assume free online dictionaries are complete as to all words existent in a language.
Where do you believe that I assumed that?
We'll never see the benefits (Score:2, Interesting)
Proven medical treatments, such as silver, acupuncture, homeopathy, etc. (proven not by a few piddly years of research, but in most cases many decades or centuries of use) will never be embraced by the mainstream medical establishment as long as the pharmaceutical companies are allowed to dictate medical policy and control the way we are permitted to keep ourselves healthy.
And you get this cool gray skin color! (Score:2)
--
Benjamin Coates
Re:We'll never see the benefits (Score:2)
Actually these things exist and you can buy them to clean a pool. My understanding is they either just invented a better way to move the fluids around inside the device so more of the water touches the Na+ and Cl-, or they are just trying to let more people know about this. The real reason this won't become widely used is that clorene is a chemical byproduct of creating fertilizer, which just happens to be a pretty good disinfectant. The most widespread adoption will do is decrease the cost of clorene and increase the cost of fertilizer slightly. They chemical companies that produce clorene could pay you to take it and still make a profit since fertilizer is such a boon to farmers.
Not that I don't think chemical companies would resort to dirty tricks. They just don't need to for clorene to be produced. It's good for their profit margins if fertilizer is cheaper, but not essential for the industry to exist. The only way it would seriously hurt them is if they couldn't pay people to take it, and had to pay for dumping it. Presumably after combining it with something to make it neutral.
See Quackwatch about colloidal silver (Score:4, Informative)
Re:See Quackwatch about colloidal silver (Score:2)
Turn you "permanently gray"? Like a photographic plate? Please...do a little more research. Are your eyes gray? Mine aren't...and if you were born in the US, you got a dose of silver nitrate right after you popped out at birth.
It's people like you, closed-minded, but otherwise intelligent, who (1) believe everything they read on the web, (2) think that the government is here to help us, and (3) believe the medical industry doesn't let profit margins get in the way of keeping people healthy.
To quote you, give me a break.
perhaps a bit too strong (Score:2)
The real reason people don't look at such medicines is not a conspiracy but lack of economic incentive: unpatentable medicines are of little economic interest to drug companies. That's why we get dozens of useless cold treatments and no drugs for many other diseases.
Picture of lady who took colloidal silver (Score:3, Interesting)
Re: Homeopathic Meds (Score:2)
Safe and effective (Score:2)
In fact, most new drugs don't pass the "effective" test. Most are rejects. This is good; progress comes from surviving testing. Once something has been demonstrated to work at all, there's the possibility of figuring how to make it work better. Without testing, nothing gets beyond the "sort of works, maybe" stage.
The FDA tolerates homeopathic drugs for "self-limiting conditions", i.e. things on the threshold of hypochondria, but not for anything serious. It's worth noting that all the "alternative therapies" for AIDS proposed by various activists, none are still taken seriously.
There has been, famously, at least one major attempt by the drug industry to stop a new treatment that threatened profits. This was the discovery that ulcers are a bacterial disease that can be cured with antibiotics. [cdc.gov] Drug companies were making billions selling people Tagamet and such for years, when a two-week course of antibiotics usually knocks the disease out permanently. This was discovered in 1982, but it took a decade to convince people. The Center for Disease Control made a major effort to get the word out to doctors, too many of whom get their drug info from drug company sales reps. This worked, and finally, Tagamet has been relegated to an over-the-counter medication for indigestion. That's an unusual case, but it's real.
Re:*pffpf* Proven treatments indeed... (Score:2)
I can't speak for silver (I've not done enough reading on this particular 'treatment'), but I can say that both
acupuncture and homeopathy are NOT proven treatments, nothing even close. I challenge you to produce
one paper in a reputable medical journal that demonstrates the effectiveness of these treatments.
"A reputable medical journal"? Like the AMA's journal, in which doctors subsidized by pharmaceutical firms carry on "research" in the name of objective science?
I challenge you to show me where it says the only effective demonstration of a medical treatment is to be found in medical journals. I've had friends die of cancer, horrible and lingering suffering, after being treated with cancer drugs declared "proven" by "reputable medical journals"...evidence-based medicine isn't all that it's cracked up to be. You've obviously been duped into believing anything the for-profit medical industry has to say about medicine.
Re:*pffpf* Proven treatments indeed... (Score:2)
Effective for what? Acupuncture has been tested and found effective for controlling pain;
Ulett GA. Acupuncture update 1984. Southern Medical Journal 78:233234, 1985.
Or do you think that's not "mainstream" enough to count?
IIRC, The skeptical inquirer did some research on it,
and also found that it was more effective than a placebo at pain control.
But that differing placement of the needles has no effect on pain reduction.
(Traditional acupunture claims that the placement of the needles matters.)
Alas, S.I.'s trial size was too small to be statistically significant.
-- this is not a
Re:We'll never see the benefits (Score:2)
For years the government denied that Gulf War vets were exposed to something that caused medical symptoms clearly out of sync with what would be statistically predicted. Yet anecdotal evidence clearly pointed to something they were exposed to, and it's only been very recently that the government has finally come to grips with what the non-scientific evidence has pointed to all along. Scientific research has its place in the world, but so does observational research.
BTW, there is always water present in av fuel due to condensation inside the storage containers and absorption from the air. The reason why water is dangerous is because it doesn't combust well in 4-stroke engines. Checking for, and draining, water from your fuel tanks is something you do prior to every flight. (Well, the smart pilots do...)
not exactly super-new technology (Score:3, Interesting)
H2O + NaCl + e- -> Cl2 + H2 + NaOH
is one of the most important in chemistry and has been in industrial use for well over 110 years. To say this is "not exactly super-new technology" is a HUGE understatement, since this is the same basic technology that has been chlorinating drinking water in the U.S. since 1908.
The new (relatively speaking) technology here appears to be the miniaturization of the electrolytic cell and membrane. While this is interesting in and of itself, I cannot see how this will be the big lifesaver they are claiming. One would think that most hospitals can and do purchase disinfectants already and would not really need to generate these hazardous chemicals onsite, even in small quantities. I mean, think of the risks: Cl2 (poisonous gas), H2 (explosive gas), and NaOH (caustic soda). If a hospital does not have the resources to buy these relatively cheap chemicals, why would they have the resources (electricity to name one) to buy and operate these little machines?
Just my $.02
umm... (Score:2)
2. Add Salt
3. Put in energy
4. ?
5. Profit!
Not difficult, you can do this it home! (Score:2)
Run a couple of volts through salt water, the
Na+ ions go to the cathode, the Cl- ions go the
anode and discharged to Cl which disolves to
form Sodium Hypochlorite this is the main
component of household bleach.
2Na+ + 2H20 + 2e- -> 2NaOH + H2
2Cl- -> Cl2 + 2e-
Cl2 + H20 = HCl + HCl0
HClO + NaOH -> NaClO + H20
Similar reaction will happen with any other
disolved salts in the water.
Re: (Score:2)
Criticising and debunking (Score:2)
-Sean
Will this work on the long term? (Score:2)
please keep my water include virii !! (Score:2)
Re: (Score:3, Informative)
What the fuck are viruses? (Score:2, Offtopic)
Actually that last one intrigues me a great deal. Words like hax0r, 1337, d00d and other techno-slang are catching on like wildfire. Currently they are only used in limited sub-cultures but certainly some of these words have such a strong and unique connotation that they will leak into common usage. This is a radical shift for english as it adds new characters into to language for the first time in a very long time (mostly characters have just been removed).
Re:What the fuck are viruses? (Score:2)
Nope. I'm suggesting that if we're going to debate what's right and wrong spelling-wise, the "ayes" have it. Language is not a stagnant thing that someone can write down in a book. Every dictionary ever written was obsolete the moment it was published. If you want to say "virii", have fun. If you're writing professionally, then I suggest that you use the spelling that will have the desired effect. Sometimes that effect is to convey the simple meaning of the word. Sometimes it's not, d00d
Re:What the fuck are viruses? (Score:2)
Those of us who've been around for a while recognize that d00d-speak is just a modern variant on an old theme. I first saw such slang on BBSes in the late 80s, but it really began to take off on USENET.
What people miss when they say that this or that fad of slang "died" is that no element of culture truly dies. Like a pebble thrown into the ocean, fads leave their mark, but its sometimes hard to tell. "Funk" was in the language before the 70s, but it acquired new meaning. Most of the "jive" slang melted away but some words in the general vocabulary were subtly altered.
I'm mearly suggesting that some of d00d-speak (if only the name "d00d-speak") will persist because it frames a cultural changing-of-the-guard that will be important even a few generations from now.
Certainly emoticons are a solid presence, and those will pose an even more interesting puzzle. Are they puctuation? I guess so. Are they part of english grammar? Umm...
Re:Sugar too (Score:2)
Actually they dehydrate and essentially implode.
The egyptions used honey on surface wounds, and mouldy bread on deeper wounds. THe honey worked on the same principle.
As best I can tell, the idea here is to kill bacteria by applying charge. It might not be very effective after the charge was released (for those that don't know, the salt creates a pathway for electrons to pass through the solution, but they are passed in the form of H+ and O- ions, and this gives off H2 and O2 as the electricity is applied.
Re:What about the anti-gravity angle? (Score:2)
Re:Killing bacteria is not always a good thing (Score:2, Insightful)
To compound the problem many people stop taking their antibiotics when they feel better (they have done their job right) which means that the bacteria have been exposed to a level of the antibiotic that hasn't killed 100% of the little nasties (a scientific term
To compound the problem in the western world we think its perfectly ok to feed our livestock constant doses of antibiotics even when there is no real evidence that its a) useful or b) more efficient. There is some evidence that such animals do grow slightly faster - something thats worth throwing away our furture use of antibiotics for..
It can help (Score:2)
This is NOT true! (Score:2, Informative)
Re:Antiseptics != antibiotics (Score:2, Insightful)
This looks like a good article on the subject: http://www.healthsci.tufts.edu/apua/Pubs/Articles/ EID6_01.pdf
And they can develop some resistance even to antiseptics, by pumping the substance out or degrading it. Oxygen would make a good antiseptic if it weren't for the fact that aerobic organisms (ie, most organisms) have enzymes to break down reactive forms of it.
Re:W0W!!! -- NOT!!!! (Score:2, Insightful)