Comment Re:Storing waste is easy (Score 2) 67
The boundary of the area where the uranium concentration is high enough to be worth mining is fairly sharp. Where there is stratigraphical continuity (i.e. not a faulted contact) with the surrounding rocks, the uranium remains confined in a fairly small area. Which is fairly good from a waste containment point of view.
Uranium's behaviour as a sedimentary material in a variable redox environment is complicated.. But since we're talking about proterozoic sediments we know that the effective oxygen contend was well below 1% of current oxygen (so 0.02% absolute equivalent) because it was so long before the Ediacaran-Cambrian, Ordovician and Carboniferous increases in ppOâ ; this was the period when iron was swapping between +2 and +3 oxidation states (and in the process, buffering the redox potential of the planet's surface - the subsurface was probably controlled by the Quartz-Fayalite Magnetite buffer) ; that change in oxidation for iron results in quite drastic changes in solubility (in roughly neutral water) and the same is true for uranium (uranyl, UOâââ) ions in solution. Moving any distance away from relatively well oxygenated surface waters would, as soon as the [Oâ] decreased by microbial activity, result in the uranium salts dropping out of solution.
It was always a complex situation, and I struggle to remember the details. But Oklo isn't a good argument that geological containment of radioactive waste doesn't work. Don't forget, of course, that nuclear waste typically contains 30 or more atomic species of concern, from caesium (an alkali metal) through barium (with one of the most insoluble sulphate salts in the periodic table - a major metamorphic mineral, we had a mine not far up the road) to radon (an "inert" gas, though at the reactive end of that spectrum). That's in addition to the uranium.
but a site where uranium in the ground underwent fission without human intervention seems like the opposite of what people want in nuclear storage.
Uranium will undergo fission without human intervention. That's one of the things it does. Without human intervention. We can change the decay rate of âBe to âLi by a few % (because the near-nuclear electron density is affected by the extra-atomic crystal lattice, but for uranium there are multiple intervening electron shells to considerably reduce the effect.
Amongst other things, the human-uninvolved decay of uranium nuclei by fission is the basis of a number of well-understood systems of radiometric dating. It's a completely natural thing. So obviously nuclear waste management has to consider it.
Uranium didn't "discover" the process of fission when Becquerel put it on a wrapped photographic plate in
I've forgotten the original topic of this thread - wasn't it something about irradiation some nuclear species with a specific wavelength (range) of gamma to change it's half life - well, change it's species - to something shorter and less inconvenient. Which is an idea that occurred to me when I was learngin about nuclear science as a dating tool in the late 1970s. But the problems remain as they were then : there are a lot of different nuclear species, requiring a lot of different wavelengths of gamma rays (stretching into the soft-X) ; and being mostly heavy metals (137-Cs is pretty low on the tree of products)), they're inconveniently radio-dense. Which means the radiation you bathe them in doesn't penetrate well into the core of the lump. but the prospect of making an inconvenient product (say, half-life 10kyr) into a more dangerous but shorter-lived product (say, 100 years) remains appealing.
I tried to work around the problems by envisaging very broad-spectrum GR(X) sources, and dissolving the shit (technical term) into a liquid, so as to expose thin films of the nucleides to the right radiation for that nucleus, and then pump it away for further processing. But the "dissolve into liquid" step just makes it as problematic as standard nuclear waste reprocessing (to produce bombs), and for a broad-band source of GR (and soft-X), really you're looking at the interior of a nuclear reactor