While a programmable molder would be awesome, it would pretty much by definition not be a 3D printer. There is some overlap with using a 3D printers to make traditional casting molds though. That's something we could even do with today's technology, though the surface might want some final polishing before you begin casting. I imagine laser-sintered titanium could make for adequate stamping tools as well.
There's also the possibility of 3D printers that print an entire layer at a time, rather than individual "voxels". Probably not for extrusion-based printing, but for laser sintering, optical resin curing, etc. there's no reason you couldn't have millions of individually switchable laser beams fixing your medium. That would decrease print times *dramatically*. Maybe not fast enough to compete with casting on Earth, but in a colony of only thousands or millions, how many Widget Xs do you really need to make in a month? And a large-scale 3D printing facility would be *far* more versatile than a similar-sized factory - an important consideration when attempting to bootstrap a civilization with limited resources.
Personally I think 3D printing with micro-/nano-cellulose would be an incredibly enabling technology for space colonization. Nanocellulose especially has some pretty incredible mechanical properties (Comparable strength to aluminum, extremely gas-impermeable, potentially transparent, etc. And you can produce it from the biomass waste that's a byproduct of growing food/oxygen, using only thermo-mechanical processes. So the remaining waste (and recycled prints) can be composted back into your ecosystem - an important consideration in a limited ecosystem.