Comment Re:I've seen work on this (Score 2) 75
I've had some inside access to this tech in recent past. The main problem is efficiency. It's horrendous. You lose tremendous amounts of energy doing this, and you need quite a bit of energy to maintain the compressed state. We're nowhere near mainline chemical batteries in terms of efficiency numbers, and whatever numbers they're claiming on their website are likely specifically negating some critical losses. I've seen efficiency numbers as low as 20-25%, through they can really struggle to push into upper 30s for long term storage, and can probably get above 50 for very short term (i.e. minimal compressed state maintenance costs). Still nowhere near the required efficiency numbers to competitive with chemical batteries of current gen. These people claim 75%. Odd.
Well, they're the ones who have been running a pilot plant. Presumably their efficiency figures come from their real world electrical power requirements / production. However, I must confess I share your scepticism. If we look at each component of the plant individually alongside their typical efficiencies (Compressor: 70% - 90%; Turbine: 40% - 95%; Electric Motor: 75% - 95%; Electrical Generator: 85% - 98%; Thermal Insulation: 80% - 98%) and factor in frictional / pressure losses in the pipe network (tbf will be small, but let's for now assume 5% losses, so 95% 'efficient') the overall efficiency will be a multiple of all these factors. This gives us, for the 'round trip':
Best Case: ~74%. Ok, this is essentially what they're claiming. So, their claims are feasible, assuming that they've installed 'best in class' everything, and that the motor / generator is operating in its optimum range.
Worst Case: ~14%. Slightly below your bottom figure, but given the terrible bottom-end efficiency for some types of turbines* (and I'm not sure, if I'm being honest, that these numbers apply in this scenario) that's not too surprising.
* Full disclosure. It's not entirely clear to me why the Betz limit wouldn't apply in this situation, which would limit the turbine efficiency to ~59%. I realise that the work is actually being done by the phase change, rather than simply the velocity, of the working fluid, but thermodynamics / fluid mechanics still presents conceptual challenges to me...
And it's completely unsuitable to any kind of "long term storage". This is very much a potential energy capacitor, and maintaining compressed state requires constant energy burn (which is one of the parts of it having awful energy efficiency).
Um, what? You've heard of valves right? Or taps? Picture, if you will, a CO2 fire extinguisher. Is there a constant energy burn required to maintain pressure within it? No! Just (mandated) yearly checks to see if the internal pressure is within spec. For a system that's designed to cycle over an 8 - 24 hour period this is very much a non-issue.
Finally there's just basic physics. From memory, CO2 goes supercritical at just over 30C (liquid and gas phase become effectively indistinguishable no matter the pressure you put it under). Last 10 degrees or so before that, pressure needed to maintain it it liquid form goes from something like 50 bar to around 80 bar if memory serves me right.
Not sure what your point is here. Industrial processes regularly use supercritical CO2. Why is this (^) relevant in this instance?
These people claim no cryogenics, which is 100% impossible claim.
Cryogenics is usually defined as utilising temperatures below ~120 K (-153 C or -238 F). At 1 atm CO2 solidifies at -78.5 C. Their claims in this regard are solid, unlike the CO2 they're using...
When you pressurize the gas, it heats up. A lot. You will need an incredibly powerful cooling system to keep it under that supercritical temp unless your "charging" is hilariously slow. Also this will suck up power.
Indeed, a lot of thermal mass will be required for the heating and cooling. Their illustration shows them using water, which has a SHC ~ 5 times that of CO2, and a larger single phase thermal range. Factor in phase changes and, once more, water's latent heat of vaporisation is much larger (~ 7 times) than that of CO2. In other words, you'd need, at most, one fifth the mass of water, if, and it's a big if, the temperature variance of both substances is the same. But it's not. The temperature range of the CO2 isn't going to vary that much, most of the energy will come from / be used in it changing phase (~348 KJ/kg). Factor in water's SHC (~4.2 KJ/kg/K), and limiting the acceptable temperature range of the water to, let's say 50 K you'd need (as an absolute minimum estimate) ~1/500th** the mass of water to 'buffer' the (temperature and) phase changes. 2000 tonnes of CO2 -> 4 tonnes of water -> 4 m^3 of water -> a 6' x 6' x 3' water tank.
How ever will they manage to build a system with such onerous requirements?***
** Again, full disclosure. Even I am doubting this figure. It seems ridiculously low, so my sarcasm above might not be warranted. You're definitely going to want to check my maths before relying on anything I've written above.
*** Yeah, I've obviously brushed past issues regarding (de)pressurisation temperature changes, and how the system actually manages the flux, but these are not new or unsolved problems. Heat exchangers are a thing. More water than my back of a fag packet calculation suggests will be required. Parent is also correct that there will be (potentially significant) pumping losses involved in such a system, which have not been factored into the overall efficiency calculated at the start.
But there's a lot of evidence pointing at it being just another ESG green credits mill, and very little evidence of it having such a breakthrough.
It's a compressed gas battery. They are not new. It's not a 'breakthrough', it's a logical extension of well understood physics and engineering, with the only novelty being the fact that it's utilising CO2 as the working fluid and that the system might be cheaper than Li or Na batteries.
Hyperbole will be the death of us!