Comment Re: Not terrible, which is too bad (Score 1) 75
Though realistically, because 240Pu (from waste) is worse in a fission bomb than 239Pu - generally no more than ~20kT, and challenging to get more than a few kT - still enough to take out a city centre but not a metro area - you'll generally want a fusion weapon, which means deuterium and tritium supplies. And Ukraine doesn't run CANDUs, so you're not going to get tritium from the coolant. They'd need lithium targets / lithium in the coolant to breed tritium. Separation of tritium and deuterium are a mix of chemical, electrochemical, and/or physical separation, but are much easier than uranium isotopic separation (deuterium is double the mass of protium, and tritum triple the mass, so the chemical / electrochemical behavior is actually notably different in a lot of situations, unlike uranium).
For a fusion bomb they'd also want a depleted uranium tamper, but Ukraine probably has ample access to that, whether from weapons, armour, old Soviet stocks, etc. Even spent nuclear fuel is mostly 238U, if they don't mind the tamper being highly radioactive.