It's a brilliant idea - in theory. Just remember that this sort of thing doesn't happen in the wild. They're also not intelligent. Who know what will happen. In fact, you may make matters worse by attracting more ant colonies near your home to stage the next future invasion. After all, that pheromone bomb is enticing even if worthless to them.
My point is that this theory should be tried and tested elsewhere first and not use your own home as a test subject. Otherwise, you could be taking a step forwarded while taking two steps back in the process.