Sure, but those are in higher end notebooks, and the market for those is probably smaller. I'd imagine the vast majority of notebooks sold are going to be cheaper ones that have a medium power chip of some kind, likely an i3. Then you'd have a bunch of utlrabooks and a bunch of high power ones, but not in remotely the same sort of quantity. Since the XPS 13 is an ultrabook, it's going to be strictly limited to the ultrabook (U-series) processors, for thermal reasons if nothing else, which is why your "call me when they have i7" comment doesn't really make sense in context.
The U-series processors come in 15W or 28W, and the XPS 13's i5-5200U is a 15W part. So it's *VERY* far away from being able to handle the TDP of a quad-core i7. The lowest power quad core chip is the fourth gen 37W i7 chips, so more than double the power and thermal requirements.
Only the U chips are out for 5th gen, so if we want to compare the fastest i5 (dual-core) with the lowest power quad-core i7, we need to look at those fourth gen 37W parts. In that case, we can see the i7-4712HQ is the fastest 37W i7, and the i5-4340M is the fastest 37W i5. The primary difference is the doubled number of cores (and cache), but the clockspeed suffers somewhat.
The i7 is looking at 2.3 to 3.3GHz, while the i5 is looking at 2.9 to 3.6GHz. The i5 also has a slightly faster GPU, 1.15GHz versus 1.25GHz. The i5 also has a few extra features, namely vPro and trusted execution. Most people won't care about those.
I'd argue that in most common scenarios, the i5 is going to be faster, because most things that the average user does is going to be limited by single-threaded performance... but some people do use applications that could take advantage of more than two cores. It'll be up to the use case.
Personally, I'm happy with an 11.5W or 15W chip in my system, because I'll take 15 hours of battery life in a system that's fast enough, versus the extra processing power that would be useless to me in a notebook. For me, the notebook is primarily for running a browser and remote desktop, and anything heavier than that is going to happen on my desktop. Perhaps even remotely, modern remote desktop provides a very close to native experience, even over LTE. For example, even full-screen video works fine over a cellular link, although I've noticed the audio is a tad delayed. It's a huge improvement over remote desktop even a few years ago.