I've used MySQL for years...
The same thing in MySQL would have taken me thirty seconds now, and no more than 15 minutes when I was starting out. With Postgres, it took me upwards of 20 minutes when it should have taken much less time.
That's because you know MySQL, so of course something that works differently is going to be more work for you to figure out.
I've used PostgreSQL for years, when I had to set up a MySQL database for some php app it took much more than 15 minutes to figure it out and get it running. The primary problem was MySQL's obtuse user management system.
With PostgreSQL I know that it's secure by default -- the default user has no password, so even if you enable password authentication it won't work (because it has no password!). You log in locally with trusted authentication, and issue the very logical CREATE USER. Edit the self-documented config file to allow remote hosts to access the database using your preferred authenticaion method, and you're done.
With MySQL, new users are automagically created by the GRANT command?! Huh? On top of that, passwords are apparently specific to a certain host string. Bizarre. Do I need to use localhost for the actual machine name for local users? What about remote machine without a reverse DNS entry? What's the order of precedence for '%' vs a more specific name?
Oh, the default 'root' account has no password ...and allows access over the network. Wonderful. Okay, so to change that do I use root@% or root@computer? How do I know I changed the right one and there isn't still some root@something entry? SHOW TABLES is easy enough, how about SHOW USERS? Nope, that's not it.
Time to check the startup guides. Well, one just has a single password change, another has 3 or 4 lines of 'delete from user...'. The reference for GRANT just has a bunch of caveats and warnings, and the "User Account Management" section goes on and on and somehow doesn't manage to tell me what I want to know.
To this day I'm not 100% sure if the MySQL install is secure. I decided my time would be better spent eliminating the MySQL-isms from the app in question so that it can run on Postgres like everything else on the server. There are some very strange queries in there - a lot of GROUP BY expressions that make no sense and aren't valid SQL. Some of it I'm not sure how it ever worked.