LG Chem batteries (speaking here as both the owner of a Bolt and the VP of Engineering for a company that does large scale stationary batteries, many of which are LG Chem) are particularly flammable. The NMC cells used in cars are more volatile than the BESS formulation - at this point we're no longer trying to do 1 hour BESS systems, so they need to dispatch a given MW usually for 4 hours. Even for solar smoothing that's a pretty gentle operation compared to a car - where my 66kWh battery pack in my Bolt could go from putting 90kW to absorbing 30kW in 3 seconds when I crested the top of my mountain in the Catskills.
So cars, particularly the NMC used by Chevy and the NCA used by Tesla, are going to be more flammable. For the BESS batteries we use there's a testing regime called UL9540A, and that looks at how flammable the cells, modules, and racks are, and how like a fire is to spread. But it also does something else, which is look at the LFL concentration of explosive gases off-gassed when cells hit thermal runaway, and one of the most crucial pieces of that analysis is whether we can get to a deflagration event, particularly a detonation, where "a fire is moving faster than the speed of sound". I can assure you, we have paid extra money for deflagration panels, gas sensors, and manual purge systems to lower LFL, and explosion is absolutely a possibility. If it is possible for a BESS, it is more likely for a car because the chemical formulations of a NMC for BESS are less volatile than the NMC for a car pack. It is possible that the nature of the pack container on a car does not allow the gas buildup that causes this, but I doubt that... since there's a passenger compartment right above the pack.
This is cell and pack specific. So for example, the Samsung E3 is a NMC battery that is largely immune to propagating fire. The LG Chem JH4 on the other hand results in "a puddle of molten aluminum" when it burns one vendor's container "down to the screws". As noted below, LFP is largely immune to this problem, and so is LTO, but both of those chemistries are probably not dense enough for cars even in the future, although one company in China is using LTO for buses.