The layer of air refers to different velocity gradients in the air. I'm not sure what you were thinking it refers to, but by not having a separation layer, you're basically making it such that a relatively small number of molecules (as in 02, N2, etc.) ever even come to rest on the blade of the fan. Dust, no matter what it's made of, is many of orders of magnitude larger than these molecules, and as such will never come to rest on the blades except on manufacturing defects, and even then, it will only do so rarely.
Sure, there will be a way for dust to build up, but this design will lead to an incredibly slow build up of dust compared to normal heatsinks.