You can't just cast aside false positives, though. It's as if you're asking what's wrong with murder on the presupposition that nobody is ever hurt.
This particular method of censorship also reverses the burdens of proof. Rather than the government going to court to prove that a defendant has something illegal or that a site should be blocked, it appears that the government has carte blanche proscribe access to sites; presumably people will now need to sue to have their material unblocked, rather than the government suing them. This can be rather burdensome, particularly for people who are on the margins of society.
How can you do 'New Math' problems with an 'Old Math' mind? -- Charles Schulz