WRT higher frequencies, In a former life I worked as an industrial sparky and as a linesman for Amtrak.
Amtrak uses 100Hz for the signal system. We were warned to not wear steel-toe shoes around the system due to the heating danger of contacting the signal system at 6.9 kV. (Examples were cited of people with severe burns from keys or coins in pockets.)
And, in an industrial job, we wired a system that used 10kHz for heating the moulds for battery terminals used in big (30 cm diameter x 50-60 cm high) cells used as backup power for telephone exchanges, etc. This power system needed to be constructed with aluminium conduit and junctions, etc since steel would have melted.
So, while I cannot comment on the direct health effects of higher frequencies, the indirect heating effect would be a significant hazard.
Since I've worked in both the US (60Hz) and Australia (50HZ) I can offer the following anecdotal information. While finalising the connection of a house in the US, (connection to the utility above the meter) I got between the active and neutral at 120v -- I'd have to say that it was probably the worst buzz I've ever had. I was sweaty and the connection was between the right hand and the left shoulder -- damn near knocked me off a 5 meter ladder.
In Oz, I was coiling a handline while standing on a ladder between the neutral and white phase or a 240/415 distribution system. (Yeah, it was stupid, but it's one of those things that you do when you're in a hurry.) The backs of my hands hit the conductors. It was nothing compared to the US number. (But then again, that might be because I immediately broke the circuit.)
Looking at what I've written, I believe that I am saying is that there are a lot of factors involved and that you cannot point to any single factor in isolation.
-Don