I know what you are referring to as far as the "Corporate Gmail" but the user didn't specify which he was referring to, however, I would imagine that running your own Exchange Server or "Outsourcing" your email would likely have comparitive costs.
"Outlook is slow and cumbersome to use"
-I don't know what version of outlook you're using or what hardware you're using it on but I don't have those issues with Exchange or Outlook. I am a BSD/IMAP/QMAIL Guy myself but Exchange 2007/2010 paired with Outlook 2007/2010 on proper hardware works just fine when properly maintained and configured.
""collaboration options"? In Outlook? What are you talking about?"
-Referring to Distribution Lists, the Outlook Calendar, Shared Calendars, MS Communicator, all would be lost in the move to GMail. Often these options can help different deparments (i.e. Sales, Marketing, Administration, etc) together in one application, even across different Operating Systems (Using OWA).
"As for him being fresh out of college, I don't know what college he went to, but in my reading, it seems like most colleges and universities these days are locked into Windows, and even teach only MS technologies in their CS departments."
-This couldn't be farther from the truth. While most universities teach heavily in windows, most computer science classes focus on Linux and in some cases Solaris. Most younger professors preach Linux as the cure all to Windows Issues.
Over all what I am saying is a Unified Hardware/Software plan properly installed and maintained is cheaper on the Administrative Costs than a 3 Teired Windows/Linux/Mac Setup.