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Comment Internal energy can't negative, not temperature (Score 1) 361

As many pointed out, internal energy of the quantum system can't be less then some zero-level > 0. On the other hand, temperature is statistical property and if we extend it to non-equilibrium systems, it is possible to have inverse population of energy levels, which resilts in negative velue for temperature. (gas lasers) p ~ exp(-e/kT)

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