The temperature and pressure at which water boils are interrelated. If you access a "steam table" from an engineering thermodynamics textbook, look at a table entitled "properties of saturated water, temperature table," you will find an entry called "saturation pressure." That is the pressure at which water boils at that temperature. If you look at something near your body temperature, say, 38 degrees C, the pressure is about 0.066 bars (or about .066 atmospheres). If you are in the upper atmosphere or in space with no pressurized suit and the pressure is below 0.066 atmospheres, your blood will boil.
This is not a complete answer to this question, however. There are concerns about bubbles of nitrogen ("the bends") due to rapid depressurization, etc. that also need to be addressed.