At a certain point you end up with, "if the Nazi's weren't the Nazi's, Germany could have won WWII". While breeding of Plutonium does occur in commercial reactors to some degree, much of it is burned up by the reactor as it operates, you also end up with a variety of Plutonium isotopes which make it almost impossible to construct a bomb. Pu-239 is what you want, but reactors also produce Pu-241 and Pu-242 which are intense neutron emitters that cause pre-detonation. Reactors designed for Plutonium production allow samples of U-238 to be placed in the reactor for short periods of time so that Pu-239 and be bred, and then removed before too much Pu-241 or Pu-242 builds up (however even in these cases, there is still enough pu-241 to cause challenges). The vast majority of commercial reactor designs can't do this.
The other big challenge is the scale of industrial facilities needed to produce fissile material at scale. Sure, Germany built the Mittelwurk to produce V-2s in a secure manner, but this was nothing compared to the size of places like Hanford or Oak Ridge. Either Germany would need years to build massive underground facilities for them, or they'd be built in the open, and bombed flat the moment the Allies found them .