What's you're really doing is using photosynthesis, a form of solar energy, to produce your fuel. Fun fact : most crops are between 1-2% efficient at converting sunlight to chemical energy. Then, you're going to lose at least half of that energy converting the crops to ethanol, then you'll lose 2/3 of the energy in the ethanol when you burn it for motive power.
Also, those crops need water and fertilizer, generally, costing you energy. If you use the good fertilizer, you won't even gain energy doing this.
Or you could use cheap Chinese made solar cells (less than $1 a watt) and use it to charge batteries. Commercial solar cells are 7-14% efficient, and the battery charging is around 80% efficient or better. When you drive the car on those batteries, another 80% or more of that power actually propels the car.
Do the math. The problem today are the high technology items needed to make all this work have high manufacturing costs (that are falling rapidly). However, in the long run, it seems pretty obvious where this is heading.