Since this is an area of interest for you I have previously done some work in industry for using what we considered something approaching an organic covalently bonded crystal (excuse the specific wording here - how sure we were of what was happening was a big worry for us)
Anyways we were looking into some work on reticular chemistry (google the phrase - a lab from UCLA should pop up) - and using the same concept to create photoconductive organic thin films without the need for much structural support. It's an area of chemistry I find extremely promising (I am not a chemist) but from what I see most of the work seems to be in creating super-porous materials but I see no reason why you can't create these highly structured films using organic molecules that have electrical properties that we want.
I'm not sure if that area is of any use for you but take a look at the structures they've made, and the proof they have that they exist (they were able to get some very convincing XRD patterns for a wide array of configurations which matched up to theoretical calculations)
Miind you in our attempts to replicate it using some custom made photoconductors we were only able to get vague peaks which required you to not wear glasses to see...
Anyways the beauty of these was processing them was easy...once you had the starter molecules ofcourse. Conditions to form the structures were low temperature bakes for less than an hour in general. If a surface is activated properly I think it would be very feasible to say just spin coat the solution, and start your bake and hopefully you end up with a film which is stuck to your surface right where you want it...but now I'm being an engineer pretending he has a clue about chemistry...
Anyways back on topic - I totally agree with your last paragraph. It's nice to see significantly fewer sensational articles than I remember seeing in the field. Even in the past five years alot of the research getting out has been less grey goo look how skynet's going to take over to much more reasonable reports. What I especially love is the amount of interdisciplinary work I'm starting to see where these highly specialized chemistry groups are actually working with engineers and the like to get some feasible processes down. It's not nearly as common as I'd like but it's starting to get there....