My FreeBSD box has to be seven or more years old. It's gone from one of the 5's through 9.0 without a reinstall. I don't use it 24/7 (but I have). Its primary purpose is to be my cvs code repository. To tech-date the system, subversion was just emerging, hence, cvs. Probably should go git.
I did use a FreeBSD system for a desktop, but this was for a year and a half around 2001. I got an iBook in September 2001, but I had already left the Windows fold for my home computing, so the desktop went FreeBSD. I do prefer OS X because of the gui integration. For a small business where I was the de facto IT guy, I used FreeBSD/squid for a web proxy and solved some huge problems with an ancient Windows SMB server at zero cost: I had used an off lease machine that was constitutionally unsuited for the business's CAD work.
Documentation for BSDs is great. I was considering a wipe and reinstall, as the path of least resistance, as I went from 8.2 to 9 yesterday, but I ate my veggies, built character, and went and looked up the step I had forgotten from the last time a version upgrade occurred. An up to date manual for FreeBSD is available at www.freebsd.org. It also is downloadable as part of the system sources and the local version is kept in sync via cvsup/make. At the site, you might find the release engineering, errata, and security update histories illuminating.
PC-BSD has some interesting ideas and I do run it virtually. It has had application sandboxing for a while, which is something I see the popular, consumer oses implementing. The project is also working on the package dependency issue and I like the way they are thinking. So, while PC-BSD is relatively new, the project keeps its kernel and userland synchronized tightly with FreeBSD. They got good folks there and I expect that its stability should be good, though not as good as FreeBSD, because of the concerns with third-party windowing parties.
Now, as I look at your summary of your problem, I'm not sure that it quite makes sense as a general question for guidance. The computers that are off-lease have to be 2 or 3 years old. You don't need seven more years from them. If you could, you'd have put Windows 7 on them. Well, PC-BSD is no more a substitute for Windows than Windows is a substitute for PC-BSD. (Yes, that's right, if one has set up a productive Unix-like environment, then Windows is a degraded experience, with quite a few "You can't get there from here." issues.) I hope this isn't a case when someone sets up a problem in order to have others offer suggestions that are swatted down, because the constraints are such that it has moved out of the power spot of the technology being discussed. Besides, the applications are far more important than the underlying os in terms of box longevity. If the cost of wiping and reinstalling saves thousands of dollars in licensing fees, well?
Any way, to summarize, you need seven more years of Windows or Windows-substitue usage from your computers and Windows 7 is too expensive, there's only to be one more wipe and reinstall, Linux doesn't help you out, and the BSDs, with their windowing systems being orthogonal to the kernel development, though very stable, may not support the applications and processor that you want to keep using. Then, I wish you good luck, because I don't think any one else other than you is trying to solve your precise problem.