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Comment Some background (Score 5, Informative) 117

Here's some background on the Bosch Haber process.

Whether a reaction will occur is based on whether energy is required and whether the reaction increases entropy. In the case of nitrogen+hydrogen => ammonia, the reaction is both exothermic and increases entropy at room temperature and pressure. If one could somehow ignite the process it would be self-sustaining.

The problem is, to ignite the reaction you first need to break N2 molecules into individual N atoms, and this requires a great deal of initial energy which is regained in subsequent steps. Something like 7eV per molecule to break them apart. The molecules in normal air have a bell-curve spread of energies, but very few of them reach energies this high: the reaction happens at room temperature, but very *very* slowly. A handful of molecules per second will react.

To get around this you can raise the temperature, increasing the probability that molecules will have enough energy to break apart. The entropy produced is inversely proportional to temperature, so when you start to have N2 molecules with enough energy to break apart, the reaction is no longer favored because it would result in an entropy decrease.

Since 4 moles of reactants result in 1 mole of product, increasing the pressure of the reactants will tend to favor the products, so you can use this to offset the deficit in entropy.

The Bosch-Haber process tries to find a "sweet spot" by increasing the temperature to get a reasonable number of N2 molecules to break apart, and high pressure to make the process favor the products.

At 200 ATM and 400 degrees, the yield is 15% (!).

Reaction vessels for this pressure and temperature are expensive, and the process requires multiple cycles of compression, decompression, removal of ammonia, and recompression. This takes a *lot* of energy and uses *very* expensive compressors which wear out over time and have to be replaced.

I haven't read the paywalled article yet, but if I'm understanding the abstract, they are breaking apart the nitrogen electrochemically. Just as running a current through molten NaCl will break it into atomic sodium and chlorine, running a current through nitrogen dissolved in KOH and NaOH breaks it apart and the reaction then proceeds at normal conditions. The reaction also supplies its own hydrogen by breaking apart water.

Much of the "green revolution" is due to the use of nitrate fertilizers, and the source material is finite: guano from Peru, for example.

If this process is as efficient as the abstract suggests and can be industrialized, it would be *huge*. It would give us an essentially infinite source of nitrogen-based fertilizer and reduce the worldwide consumption of energy by a couple of percent.

Coupled with a source of renewable energy, it would mean that the world could sustain its food production at current levels indefinitely.

This could be really, *really* big news.

Comment 1920x1200 monitor (Score 1) 286

I like that resolution, too. Reasonable balance between not enough room and dealing with all of the font/scaling issues of the higher-resolution monitors. One of my compadres chose the lower resolution of two high-resolution monitors because the higher just didn't look right in side-by-side comparison. Besides, I look at the monitor much more than the TV, so it should have "more", too.

I recently picked up a Dell U2412M, and may order another to keep as a spare.

Comment there IS a connection (Score 5, Insightful) 151

I used to work for one of the In-Flight Entertainment (IFE) vendors. Although their "architect" was clueless about security, some of us doing the work managed to build some into the system. With WiFi, it was harder, but, before I left, we had, at least, set up some VPNs to isolate the system control links from the cabin crew- and customer-access features (don't know if that persisted). The entire IFE did rely on hard-coded passwords, though.

There IS a connection between the IFE and aircraft systems. It is used to feed aircraft position and speed data, plus some useful state, such as wheels up/down (there are features that only enabled while in "cruise", but not during takeoff and landing, for example). The aircraft systems designers, however, seemed to have a clue about security, however, as we were only allowed a network connection to a slave server with no apparent upstream links.

Comment corporate welfare for the scum of the Earth (Score 2) 207

Wanna sue the gov't for something meaningful? Sue to get ALL of it (DHS, FBI, local cops, whatever) away from filling the welfare trough for the studio scum.

The Blu-Ray for "Under the Skin" has 11 MINUTES of uninterruptible BS before the menu (but, yes, she IS that hot). The torrent is a better product; "let the marketplace decide".

Comment or "Ouya" (Score 1) 188

I've got an Ouya, specifically to run XBMC. Runs pretty well with both the controller and a keyboard+mouse, except that the mouse speed is a bit high. Yes, it could use GigE and USB3.0, but running from the NAS it's fast enough and upscales what I've used, so far, in real time. Haven't found a good Linux Blu-Ray-to-stream converter, so no testing with those.

Comment Re:FUD filled.... (Score 1) 212

It sounds like this transformer had its center tap grounded and was the path to ground on one side of a ground loop as the geomagnetic field moved under pressure from a CME, inducing a common-mode current in the long-distance power line. A gas pipeline in an area of poor ground conductivity in Russia was also destroyed, it is said, resulting in 500 deaths.

One can protect against this phenomenon by use of common-mode breakers and perhaps even overheat breakers. The system will not stay up but nor will it be destroyed. This is a high-current rather than high-voltage phenomenon and thus the various methods used to dissipate lightning currents might not be effective.

Comment almost should have let her call (Score 2) 928

If there was any good chance of a reasoning being on the other end of her call to the police, it would have been worth it to let her call and then have the LEO "explain" to her the (unfortunately rare) consequences of filing a false complaint, then watching HER be arrested for disrupting the flight. As it is, of course, ...

Comment wrong place for solution (Score 1) 550

Myopia is the effect of having an eyeball out-of-round. Astigmatism is the result of aberrations in the cornea. Why cut up the cornea to fix myopia? You got lucky with 20/15; most do not, and many have aberrations. No thanks.

If/when myopia-corrective lens implants give full vision range (and, incidentally, also correct presbyopia), I'll be down to the clinic to have it done. Until then, I have 20/15, 20/20 and astigmatism correction with contacts and no side effects.

Submission + - Letter to Congress: Ending U.S. Dependency on Russia for Access to Space 1

Bruce Perens writes: I've sent a letter to my district's senators and member of congress this evening, regarding how we should achieve a swifter end to U.S. dependency on the Russians for access to space. Please read my letter, below. If you like it, please join me and send something similar to your own representatives. Find them here and here. — Bruce

Dear Congressperson Lee,

The U.S. is dependent on the Russians for present and future access to space. Only Soyuz can bring astronauts to and from the Space Station. The space vehicles being built by United Launch Alliance are designed around a Russian engine. NASA's own design for a crewed rocket is in its infancy and will not be useful for a decade, if it ever flies.

Mr. Putin has become much too bold because of other nations dependence. The recent loss of Malaysia Air MH17 and all aboard is one consequence.

Ending our dependency on Russia for access to space, sooner than we previously planned, has become critical. SpaceX has announced the crewed version of their Dragon spaceship. They have had multiple successful flights and returns to Earth of the un-crewed Dragon and their Falcon 9 rocket, which are without unfortunate foreign dependencies. SpaceX is pursuing development using private funds. The U.S. should now support and accelerate that development.

SpaceX has, after only a decade of development, demonstrated many advances over existing and planned paths to space. Recently they have twice successfully brought the first stage of their Falcon 9 rocket back to the ocean surface at a speed that would allow safe landing on ground. They have demonstrated many times the safe takeoff, flight to significant altitude, ground landing and re-flight of two similar test rockets. In October they plan the touchdown of their rocket's first stage on a barge at sea, and its recovery and re-use after a full flight to space. Should their plan for a reusable first-stage, second, and crew vehicle be achieved, it could result in a reduction in the cost of access to space to perhaps 1/100 of the current "astronomical" price. This would open a new frontier to economical access in a way not witnessed by our nation since the transcontinental railroad. The U.S. should now support this effort and reap its tremendous economic rewards.

This plan is not without risk, and like all space research there will be failures, delays, and eventually lost life. However, the many successes of SpaceX argue for our increased support now, and the potential of tremendous benefit to our nation and the world.

Please write back to me.

Many Thanks

Bruce Perens

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