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Journal Journal: Why doesn't the solar cell industry obey Moores Law?

Another tediously typed up comment that was lost in the flood (What Gore Didn't Say About Solar Cells)

Lets have a look at actual data: []

During the last decade there was only a very mediocre decline in manufacturing cost per watt. Scaling up solar cell production in the last few years actually brought prices up again due to silicon shortage.

However the price of solar cells is expected to decline sharper during the next years

1) Many new solar grade silicon fabs are coming up, hopefully driving down the cost of solar grade silicon

2) Thin film solar cells which can be produced at lower cost (but at the expense of efficiency and reliability) are gaining more and more market share and are improving.

As many other people pointed out, the scaling of solar cells is inherently different from that of microelectronics. In integrated circuits you are actually able to reduce the size and increase the density of your circuits.

For solar cells the material consumption per watt is pretty simple:

Vol [cmÂ/W] = thickness [cm] / efficiency [W/cmÂ]

Efficiencies for mass products are currently stuck somewhere between 15% and 20%. There are limited ways to work around this (concentrator cells, multijunction). This figure of merit is not expected to scale.

Reducing the material thickness is obviously the only option. Since the material thickness depends on physical properties (direct/indirect band gap) there are hard limits as well.

It boils down to the fact there there is no technical scaling model or road map to improve solar cell similar to integrated circuits. The main lever is simply in manufacturing intelligence and cost.

Personally I think the most interesting ramifications of this are that we will see (short lived) phase where companies can survive based on superior manufacturing technologies. Over time these differentiators will becomes less significant and cost is only defined by environmental factors such as cost of energy, raw material and labour.

This is why the solar cell industry will not be a pleasant place to work in in ten years, as interesting as it looks now. Outsourcing and consolidation will be swift and brutal. Even today companies are looking into places such as Malaysia, Mexico, Mongolia (!).

User Journal

Journal Journal: Comment about electrocaloric refridgerators

There has been quite some hype about 'compressor-free refridgerators'. Just some notes saved from comments I posted in the article. Probably gibberish to you if you are not a material science geek.

There are many ways to induce first order phase transitions in various system, leading to the release or take up of heat.

The special thing about the device in the article is that this phase transition is induced by an electric field, the so called electrocaloric effect. Therefore no movable parts in the system are required. Previously only small temperature differences have been demonstrated in metal oxides (small than 10K). By using ferroelectric/antiferroelectric polymers they are apparently able to increase the temperature difference to above 10K, which is a very significant increase.

That said, this of course typical university hype science and practial application faces many engineering and also intrinsic scientific problems. First of all they have not measured the temperature difference, but deduced it indirectly from maxwell relations. In a realistic set up the temperature difference will be lower.

A second problem is intrinsic to the material and has been conveniently neglected: Since the principle relies on a solid insulator the heat conductivitiy is extremely low. (No convection, no electronic heat conduction). This means that you are able to create a temperature gradient, but are not able to transfer a lot of heat, thereby severely limiting the cooling ability.

A third problem is that this effect only works in a very limited temperature range (above 70C). A fourth problem is hysteretic heating due to ferroelectricity...

Link to the original article: click

older work by the group

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