Counseling and Networking/Telecom are not "short term" one week fields - Networking and Counseling are not like medicine where you can do quick meatball surgery and fix immediate problems.
For your wife to be of any value she would need to form a therapeutic relationship with people, which takes time and trust. This won't happen in a week, and such short term "counseling" may end up doing more harm than good.
For you to do any good you would need to engineer a solution to some problem (could take more than a week in itself) and be available to help with deployment, which could stretch into months or longer depending on the scale of the project.
If you want to volunteer I suggest finding local causes - Your wife could work a crisis center hotline one night a week, and you could volunteer at a local non-profit that needs the networking help but can't afford a full-time guy.
If you want to help out a stricken region but can't commit to a month or longer I think your money is more useful than your time (and probably tax-deductible).
Construction and Demolition specialists are needed to repair (or demolish and rebuild) structures.
For many of the people in those categories Haiti will be their first "real" disaster scene. Others may have previous experience and volunteer to help even though their "day job" isn't rebuilding nations after a catastrophic event.
While I agree that people should only go into a disaster area like Haiti as part of an organized recovery effort I don't believe the "Don't go there because you don't work for [insert disaster group]" attitude this post and the grandparent take is at all productive - These organizations do not have the manpower or expertise to do it all themselves.
Just my $3.50 as someone who has gone in after fires and floods to bring skeleton infrastructure up and support further recovery.
Those who can, do; those who can't, write. Those who can't write work for the Bell Labs Record.