The reason Eve can't just generate a new pad is because there are two methods of generating a photon and two methods of measuring a photon. Each method of generating a photon has a matched way of measuring it. If you use the matched measurement method you correctly get the bit Alice sent. If you use the incorrect method you get a random 0 or 1 no matter what bit Alice sent. Eve (and Bob too) has no way of telling which method Alice used. In quantum key distribution, after sending the photons, Alice would contact Bob over a different channel. They would tell which method they used, and if they used matching methods keep that bit. If they used different methods they would throw out the bit. If Eve regenerated the bits, she could not have used the same methods as Alice since she doesnt know which methods were used. So Alice and Bob's keys won't match up which will result in any information passed between them to be undecodable and they will know someone eavesdropped.
Quantum Key Distribution is, in its most naive form, still vulnerable to man in the middle attacks. It makes it a little more difficult because you must be able to intercept information on two different channels (the quantum channel and the classical electronic channel), but it is still doable. (There are, however, cryptographic methods of detecting man in the middle attacks, but thats a subject for another time).
