DC can be problematic in that you can't always detect certain faults as there is not ground fault current, so there is inherently some greater chance of something like a bad connection overheating and causing damage, but that should not really be a concern if stuff is quality and installed correctly.
There's no connection between ground faults and bad connections that might cause overheating. But to the extent that DC systems might have lower voltage and therefore higher current, bad connections ARE more likely to overheat and cause fires. Also, there's no reason a properly installed DC system can't have Ground Fault Interrupters, although the ones currently used for AC won't work on DC. The ones designed for DC would be somewhat more complex, and probably bigger as well.
Another note: interrupting Direct Current without arcing can be difficult. AC has a zero crossing that extinguishes an arc across switch contacts, whereas the equivalent DC circuit may continue to arc across switch or relay contacts. Such switches and relays typically have heavier contacts and the contacts, when open, tend to have more space between them. The may also have permanent magnets nearby to act as 'blowouts' to extinguish any arc that develops.