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This particular incident was the 1902 eruption of St. Pelee on Martinique which killed 30,000 people in Saint-Pierre. What killed everyone in this case was not CO2 but a Nuee Ardente or pyroclastic flow. http://en.wikipedia.org/wiki/Saint-Pierre,_Martinique
There was a survivor who was in the town jail. There used to be some items from the town in the Natural History museum in London, including half molten glasses and bottles.