I read a lot about space, and am a scuba diver, here's my take.
First, diving to 100 meters is going to be fairly dangerous, certainly not something your typical sport diver would do. Beyond 100 feet, you'll increasingly have issues with nitrogen narcosis (you feel drunk), and you'll definitely be in the realm of exotic air mixes (helium instead of Nitrogen, less than surface amounts of O2, etc...). At 100m using normal air, your partial pressure (think concentration) of O2 is 180% of surface level (been a while since I had to do that sort of math), which would be poisonous. Lets just compare to 100 FEET of depth, which a sport diver might do. You could remain at that depth for 10-15 minutes without having to decompress. Stay longer, and you need to sit at depth (say 20 feet) for a while to let the air dissolved in your blood to slowly come out of solution. Go up too fast and it's like opening a bottle of pop, but in your blood. Those bubbles can get caught in your joints, or worse spine, and cause paralysis. Divers that DO engage in deep diving are doing technical diving. Most of the gear is the same as a sport diver, you just carry more of it, particularly tanks and regulators.
But space is worse. First, space suits don't run at normal air pressure, they're down around 4.3 PSI (normal earth is 15). The ISS runs at the same pressure as earth, so donning a space suit is the same as rising UP from depth while diving, you'd get the bends as soon as you open the hatch and exit the ISS (opening the pop bottle). To solve this, when doing an EVA, astronauts breathe 100% O2 for an hour before donning and exiting the ISS.
Second, you have all sorts of cooling issues in space. Your body gives off a lot of heat, and in space, there is no place for that heat to go, so the cooling systems are far more elaborate than any warming systems (often just a hose with hot water being piped down from the surface if you were commercial diving) you might use underwater.