It has been known since the 1960's that the Sun produces energy from fusion, but the actual neutrino's observed then (and until now) were high energy electron neutrinos that actually came from relatively unimportant fusion chains (from the standpoint of energy production), not the proton-proton chain though to produce most of the Sun's energy. Since there was a "neutrino problem" (the Sun appeared to produce only 1/3 of the neutrinos predicted by theory), some people did think that for whatever reason the main energy source - the proton–proton chain reaction - was for some reason mostly shut down, presumably as part of some long period oscillation in the Sun's deep interior (although Arthur C Clarke wrote a novel, "The Songs of Distant Earth," in which it was a permanent shutdown of the Sun's fusion, and a prelude to our Sun going supernova). At that time, the inability to directly see the pp chain seemed like a big deal, but since the discovery of neutrino oscillations (which nicely explain the factor of 1/3), and also with solar interior modeling from helioseismology, there has been a pretty solid consensus that the pp chain was running the Sun, even if there was no direct observation of it.
Now it has been proved. In 1990 that would have been a big deal, but now it is more a matter of just being satisfyingly complete in our observations of the Sun.