The trouble with running 2.5kV is that it'd 'probably' be even more expensive as the power company would have to run you a line from the 'nearest' 2.5kV transformer, plus, do they really want to be running that voltage through a residential zone? It'd have to be insulated.
And run through sturdy conduit once it reached the house, preferably for the shortest most direct run possible. And you'd need some engineering work on the connectors, to avoid any potential for arcing across an air gap to anything the owner waved it near, metal stuff, fingers, etc. And even then, you'd probably want some super-sized GFCI-style cutoff for last-resort protection, and I don't have a clue how much that would cost.
You're probably looking at a hundred to two hundred a foot for the service run. Is that 100 feet or a mile?
I'd think it would have to be pretty close. They don't want to run 120/240 very far because of the resistive losses. But still, it would be expensive.
You're 'mostly' right'. You can have an 800 amp 240V service, I even found a box for it here [platt.com]. It's 'only' 4 modern home's worth.
Thing is, even the wire to carry 200A costs $4-$5 per foot, times 3 cables--just for wire. (And it's only that cheap because they use aluminum for it. Good god copper would probably cost $100 per foot just for the wire...)
But I wasn't thinking so much of the wire to the house. I was thinking of the wire between charger and car. 800A worth of wire would be enormously thick stiff and heavy, far too much so for the owner to pick it up and connect it to the car. But I suppose the charging station could have a transformer to kick the voltage way back up in order to get the power delivered through a cable that one person could actually pick up and connect. Of course now you're going through two (potentially [haha]) unnecessary transformers on the way to the car...