The head of the Mars Society is Robert Zubrin, who is a well qualified and inventive aerospace engineer. I assume the rest of their work at least involves doing the relevant math.
The Mars One project's problem isn't wanting to go to Mars, it's the missing step two in their plan:
(1) Raise around a million dollars from crowdsourcing, tee shirt sales, and application fees
(2) ???
(3) Finish $6 billion worth of space hardware and launch it.
Elon Musk/SpaceX also want to go to Mars, but they have actual rockets and customers, and his other businesses (Tesla and Solar City) both stand to make a lot of money, and are useful to the original goal. You will need electric rovers, batteries for power storage, and solar panels on Mars. It helps if you have companies that already make that stuff. So I rate the SpaceX Mars program way higher on the probability scale.