The instability that causes the collapse of a stellar core and subsequent explosion comes from turning gamma rays into pairs of electrons and positrons. This turns energy into matter and cuts the pressure that the energy provides.
http://en.wikipedia.org/wiki/P... It turns out that these explosions may make observing the early universe easier. One of the most important abundance ratios is the interstellar medium is the ratio of oxygen to carbon. The strength of the carbon monoxide bond is so strong that these two really pair up. Whichever runs out first determines the remaining chemistry to a large degree. Mass losing carbon rich stars produce carbon rich dust, while mass losing oxygen rich stars produce silicate dust for example. But, primordial Pair Instability Super Novae may produce lots of oxygen with little carbon or silicon to combine with. So the very early solid phase of the ISM may be mostly water ice. This happens to increase the far infrared emissivity of this solid phase making early objects brighter in the red-shifted sub-millimeter. Thus very early object may be easy to find in surveys at that wavelength.
http://iopscience.iop.org/0004...