I am a graduate student in astronomy and I am very active in astronomy education and outreach. There are a lot of things you can do with students with a very small set of tools. In addition to your telescope I would either bring or encourage students to bring:
1. Binoculars
2. Flashlight (red led OR take a regular flashlight and cover in several layers of red cellophane)
3. an open mind
If you then bring the Astronomical Almanac and a planisphere (star chart) you can find many of the great objects in the sky. Looking at bright stars that have different colors is a great way to start talking about what's in the sky. Betelgeuse and Rigel are great for this and they are up at the right time of night in the spring. Another great binary star is Alberio in Cygnus. It is a double star that is a K spectral type and a B spectral type (orange and blue in color). You can see them through binoculars so it should not be hard to point the telescope at it. Almost all of the Messier catalog objects should be visible with a 4-inch telescope even if they are not magnificent. This may be a way of talking to students about how a telescope works and why astronomers want better cameras and bigger mirrors. If you have students learning some of the objects in the night sky and able to point to them with and without a telescope I think you will be doing well.
http://www.heavens-above.com/ is a great website that will tell you about all fly overs of the space station, Hubble, and any iridium flashes. Some of these flashes are quite spectacular. While you cannot see these in the telescope they are fun. As for planets, no matter what telescope you use none of them are truly spectacular. As the aperture grows the amount of detail you "can" see will go up because you are collecting more light but the atmosphere will blur the images more as well. So it is a toss up at some level. I love looking at solar system objects just to see what I can see. The moon is fascinating and you can make good use of the night/day boundary to teach about mountains, shadows, and how Galileo proved the moon is a flawed object. But really my advice is to try it and look up with your students. Best of luck!